(WABI) – It happened on Meadowhill Road in the town of Greene just before 1:00 p.m. on Sunday.
The 2-vehicle crash reportedly involved a Honda Civic and a Chevy Trailblazer.
Police say the driver of the Civic crossed the center line and collided with the Trailblazer.
The driver of the Civic, Matthew Rodrigue, died at the scene, investigators say he was not wearing a seat belt.
The driver of the Trailblazer, 39-year-old Kimberly Long of Greene, was taken to a hospital with minor injuries.
A reconstruction team was on the scene Sunday afternoon to try and determine what caused the crash.